Carboxyllic acid

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 Carboxylic acids are organic compounds which contain a carboxyl group (COOH)Cite error: Invalid <ref> tag; name cannot be a simple integer. Use a descriptive title

Naming

You always name carboxylic acids from the first carbon atom on the COOH group. This carbon atom is always counted as carbon number 1 regardless of how many other side chains there are on the compoundCite error: Invalid <ref> tag; name cannot be a simple integer. Use a descriptive title.

Examples of Carboxylic acids

The shortest carboxylic acid is methanoic acid and its chemical formula is CH3COOH. Other examples include ethanoic acid, 2 methyl butanoic acid etcCite error: Invalid <ref> tag; name cannot be a simple integer. Use a descriptive title.

Formation

Primary alcohols can be oxidised through heating under reflux with potassium dichromate solution to produce carboxylic acidsCite error: Invalid <ref> tag; name cannot be a simple integer. Use a descriptive title. Other ways of producing carboxylic acids include hydrolysing nitriles through acid or alkali hydrolysisCite error: Invalid <ref> tag; name cannot be a simple integer. Use a descriptive title.

Physical properties

Carboxylic acids have slightly higher boiling points than alcohols due to stronger hydrogen bondingCite error: Invalid <ref> tag; name cannot be a simple integer. Use a descriptive title.

Smaller chain carboxylic acids are relatively soluble in water. However the bigger acids tend to be less soluble due to the hydrocarbon tails breaking hydrogen bonds between water molecules and the carboxylic acidCite error: Invalid <ref> tag; name cannot be a simple integer. Use a descriptive title.


References